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Class XI · Chemistry · Unit 4 · Lecture

States of Matter: Gases

The complete lecture — every gas law shown through an everyday object you already know: a bicycle pump, a balloon in the sun, a pressure cooker, a puff of perfume. Scroll down; the live panel on the right animates each idea as you reach it.

Block the nozzle of a bicycle pump and push the plunger. The air does not vanish — the same molecules are forced into a smaller space, so they strike the walls more often and the pressure shoots up. That is Boyle's law: at constant temperature the volume of a gas is inversely proportional to its pressure.

Boyle's law (constant T)V ∝ 1/P  ⇒  PV = constant  ⇒  P₁V₁ = P₂V₂

A graph of P against V is a curve (a hyperbola); P against 1/V is a straight line. Halve the volume and you exactly double the pressure — watch the live P · V = k readout on the right hold steady as the plunger moves.

Boyle's law
A gas occupies 2 dm³ at 1 atm. What volume at 4 atm (constant T)?
P₁V₁ = P₂V₂ → (1)(2) = (4)(V₂) → V₂ = 0.5 dm³
🚴 Real world: it is also why a diver's air bubbles swell as they rise — less water above means lower pressure, so each bubble expands.

Tie off a balloon and leave it in the hot sun and it grows visibly. Heating makes the air molecules move faster; to keep the pressure the same they need more room, so the balloon expands. This is Charles's law: at constant pressure the volume is directly proportional to the absolute (kelvin) temperature.

Charles's law (constant P)V ∝ T  ⇒  V/T = constant  ⇒  V₁/T₁ = V₂/T₂  (T in K)
Absolute zero: extrapolating V→0 gives −273 °C = 0 K, the coldest possible temperature. Always convert °C to K (K = °C + 273).
Charles's law
A gas is 300 cm³ at 27 °C. Volume at 127 °C (constant P)?
T₁ = 300 K, T₂ = 400 K → V₂ = 300 × 400/300 = 400 cm³

A pressure cooker traps steam in a fixed volume. The lid will not let the gas expand, so as the flame heats it the only thing that can rise is the pressure — until it lifts the weighted valve and the cooker whistles. At constant volume, Gay-Lussac's law says pressure is directly proportional to absolute temperature.

Gay-Lussac's (pressure) lawP ∝ T  ⇒  P/T = constant  ⇒  P₁/T₁ = P₂/T₂  (T in K)

That higher internal pressure raises the boiling point of the water inside, which is exactly why food cooks faster in a pressure cooker.

⚠️ Real world: the same law is why an aerosol can must never be thrown on a fire — the heat sends the pressure soaring and the can can burst.

Boyle's, Charles's, Gay-Lussac's and Avogadro's laws all fold into a single master equation. Avogadro's law adds that, at the same T and P, equal volumes hold equal numbers of molecules — one mole of any gas fills 22.4 dm³ at STP.

Ideal gas equationPV = nRT
R = 0.0821 dm³·atm·K⁻¹·mol⁻¹ = 8.314 J·K⁻¹·mol⁻¹

The live panel is a working gas box. Shrink the volume (Boyle) or heat it (Gay-Lussac) and watch the pressure climb; the ratio PV/T stays constant — that constant is nR.

ideal gas equation
Volume of 2 mol of gas at 27 °C and 1 atm?
V = nRT/P = (2)(0.0821)(300)/1 = 49.3 dm³

The air in a car tyre is a mixture — mostly nitrogen, plus oxygen. Each gas drums on the rubber as if the other were not there. Dalton's law says the total pressure is simply the sum of the partial pressures each gas would exert alone.

Dalton's lawP_total = P₁ + P₂ + P₃ + …
partial pressure: Pᵢ = (mole fraction xᵢ) × P_total
Use: correcting a gas collected over water — subtract the water-vapour pressure (aqueous tension): P_dry = P_total − P_water. It is also how we know the air you breathe is about one-fifth oxygen.
partial pressure
2 mol N₂ + 3 mol O₂ at total 5 atm. Partial pressure of O₂?
x_O₂ = 3/5 = 0.6 → P_O₂ = 0.6 × 5 = 3 atm

Open a bottle of perfume at one end of a room and, moments later, someone at the far end smells it — the molecules have diffused through the air. Graham's law says the rate of diffusion (or effusion) is inversely proportional to the square root of the molar mass: light molecules travel faster.

Graham's lawrate ∝ 1/√M  ⇒  r₁/r₂ = √(M₂/M₁)
Graham's law
Compare the diffusion rates of H₂ (M=2) and O₂ (M=32).
r_H₂/r_O₂ = √(32/2) = √16 = 4 — hydrogen diffuses 4× faster
💨 Real world: it is why a helium balloon goes flat sooner than an air-filled one — the tiny helium atoms slip out fastest.

Every law above flows from one simple picture — the Kinetic Molecular Theory. Imagine countless tiny balls forever bouncing inside a box, hammering the walls; the steady drumbeat of those collisions is the gas pressure.

  • Gases are tiny particles in continuous, random, straight-line motion.
  • Their own volume is negligible next to the container's.
  • There are no attractive or repulsive forces between them.
  • Collisions are perfectly elastic — no kinetic energy is lost.
  • Average kinetic energy is directly proportional to absolute temperature.
Kinetic equation & speedPV = ⅓ m N c̄²  ·  c_rms = √(3RT / M)
At the same T all gases have equal average kinetic energy, but lighter molecules move faster — which is exactly why H₂ diffuses fastest.

Heat a kernel of popcorn and the trapped water turns to steam; the molecules speed up, the pressure soars, and the kernel finally bursts. Heating any gas raises its molecular speed and kinetic energy (K.E. ∝ T) — the engine behind every effect in this lecture.

Real gases obey PV = nRT only at low pressure and high temperature. At high pressure or low temperature two assumptions of the kinetic theory break down — molecules do take up space and do attract one another — so the van der Waals equation corrects for both.

van der Waals equation(P + an²/V²)(V − nb) = nRT  — a: attraction · b: molecular volume
  1. Boyle's (PV=k), Charles's (V/T=k), Gay-Lussac's (P/T=k) & Avogadro's laws.
  2. Ideal-gas equation PV = nRT and the combined gas law.
  3. Dalton's law of partial pressures; Graham's law (rate ∝ 1/√M).
  4. Kinetic Molecular Theory; K.E. ∝ T; c_rms.
  5. Real gases, van der Waals & liquefaction.
⚛ Live panelGases
Scroll the lecture — this panel animates each concept with an everyday object as you reach it.